Batteries

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Introduction

There are a wide variety of battery chemistries available for use as the main traction battery of an EV. To use each chemistry safely, and to ensure an adequate service life from the battery pack it is important to understand the requirements for the chemistry you are using. Failure to do so may lead to premature or catastrophic failure of the pack.

Good pack design will allow for a nominal amount of abuse. People make mistakes and the pack should allow a margin for safety - and for longevity!

Battery pack specification

When deciding on your battery pack, here are some basic parameters to consider:

Capacity (kWh)

How far do you want to go? A standard car conversion will need a kWh for each 3, maybe 4 miles of range (very approximately). For a middleweight motorcycle, a kWh should give around 9 miles. Your mileage may vary, as they say.

Voltage (V)

How fast do you want to go? The pack voltage defines the maximum speed your motor can spin. Motors are usually specified with "KV" - or RPM-per-volt. Check the KV of your motor and how fast it needs to spin to get your desired top speed. e.g. if you need 3,000 RPM from a 25 KV motor then your pack voltage needs to be 3,000 / 25 = 120 V. The exact number of cells in series you need depends on the cell design, but 3.8 V for Li-ion and 3.2 V for LiFePO4 is a reasonable guess.

Maximum current (A)

How quickly do you want to accelerate? Your motor's maximum power will be specified in kW. To estimate your maximum current draw, divide the peak power by the battery voltage. e.g. a 30 kW motor with a 120 V battery pack will pull 30,000 / 120 = 250 A. The higher the current rating of the cells, the heavier they will be for a given capacity. Ideally, you want "enough" current capacity for full throttle acceleration, but no more. You can put cells in parallel to double the current rating of your pack (which of course will half the voltage). Running cells in parallel is easy, but don't attempt to parallel battery packs unless you really know what you are doing. It's complicated[1].

Mass (kg)

Can your vehicle carry the weight? You'll need to keep the kerb weight within the original design limits. For a car, your pack could be a few hundred kg. For a motorcycle, likely less than 100 kg. This is a huge variable - and each new generation of battery tech seems to be a little lighter. For older EV or hybrid batteries, you can reckon on approximately 10 kg/kWh. Nissan Leaf batteries are relatively light (7.5 kg/kWh). With the latest technology (e.g. Kokam pouch cells or 18650s), you can get this down to 5-6 kg/kWh.

Volume (L)

Will it fit? Batteries are bulky. They are getting smaller, but finding enough space might be your biggest challenge. You could be looking at over 5 L/kWh for older EV or hybrid batteries. Current state-of-the-art is the Tesla Model 3, which gets this down to 2.5 L/kWh by using 2170 cylindrical cells.

There is much, much more to battery design than this (e.g. maximum charge rate, terminations, cooling, clamping), but the above should help work out which options will or won't work for your project...

Cell chemistry

Lithium Iron Phosphate (LiFePO4)

Lithium Iron Phosphate (also known as LFP, or LiFePO4) batteries offer a good compromise between safety, energy density and ease of use for DIY conversions. They are available in a number of formats, commonly pouch cells, prismatic cells and cylindrical cells.

LiFePO4 pouch cells

The majority of this content is drawn from this thread [2] discussing the use of the A123 20Ah pouch cell. However, many of the general points apply equally to other similar pouch cells.

General build requirements

Pouch cells are vulnerable to damage from debris, and must be held in compression (see the datasheet for your battery, but 10-12 psi is recommended for the A123 pouch cells as a guide). A rigid container capable of preventing damage and providing compression is therefore required. Be aware the cells expand and contract in use, so allowance for this must be included in the structure of the case.

The pouch cells should be separated to prevent abrasion between cells, and also to avoid the development of hot spots. Prebuilt modules from A123 systems had thin foam sheets or heatsinks between each cell. Be sure to avoid any debris that could rub on the pouch surface, particularly if using recycled cells.

Mylar, 'Fish paper'[3] or a compliant foam[4] may be appropriate materials to serve this purpose. This material should not be flammable. If the material is heat insulating, it is important to address thermal management.

Compression

Compression is required to prevent premature failure of the cell. Without compression electrolyte will become unevenly distributed, causing current gradients in the cell and uneven heating. Local temperatures can become high enough to form gas formation leading to cells 'puffing up' even when the pack is otherwise held within temperature and voltage constraints. This will be exacerbated in packs with otherwise poor thermal management. Compression forces gas generated to the margins of the cell, outside of the cell stack, minimising its effect cell performance. Gas in the middle cells will create a dead space which does not store or release energy.

There is ~1% expansion through a discharge cycle. As the cell ages, the nominal cell thickness can grow by 3-5%. For A123 cells the ideal pressure is between 4 and 18psi with the ideal pressure being ~12psi. Maintaining 12psi can increase the life by 500 cycles over that of 4 or 18psi

There is some suggestion that in uses where 1C is never exceeded compression may not be required.

Highly rigid endplates with a mechanism to allow for a limited degree of expansion (e.g. steel bands) are considered an effective solution to this challenge.

It should be noted that compression is a challenge specific to pouch cells. Cylindrical cells are designed to maintain their own compression within the cell's electrode stack by their design.

This thread provides more information and experimentation relating to pack compression: https://endless-sphere.com/forums/viewtopic.php?f=14&t=52244

Pouch Cell Pack Design Examples

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Notes regarding recycled pouch cells

Pouch cells are somewhat fragile, and breaching the insulation is not difficult, especially in a cells removed from existing packs and repurposed. If the pouch has had their poly-layers compromised you may see a number of faults:

  • Black spots around the perimeter of the cell indicate electrolyte leakage
  • Voltage on the outside of the bag. Note that microvoltage between the pouch and the electrode is normal (and due to a capacitive effect).

While the majority of these cells should no longer be in the market, a significant number of faulty cells made it back into the 'greymarket' in around 2013. These cells had misaligned tabs which can also lead to isolation failures between the tab and the pack. These cells should be avoided, particularly in high demand applications.

Situations likely to cause pouch cell failure

Taken directly from wb9k's[5] post on endless sphere in the A123 thread[6]

  1. Overcharge. Any extended time above 3.8 Volts will generate enough heat and electrochemical activity to puff a cell, especially one that is improperly compressed.
  2. Overdischarge followed by charge. Any A123 cell that has been pulled low enough to come to rest at <300 mV should be immediately scrapped. The published number for that is 500 mV, but the real figure is closer to 300, so that's a "safety buffer" if you will. Below this Voltage, the Cu electrodes start to dissolve into the electrolyte. When charge is applied, the Cu forms dendrites that puncture the separator layer, forming an internal short in the cell. This can puff a cell in a hurry---the more charge current on tap, the worse it's prone to be.
  3. Driving a cell negative. I've neglected to mention this before, but it is a possibility. I don't know much about the specific mechanism at this time.
  4. Malfunctioning or misinformed electronics. This is the most common cause of all of the above in my experience. At this stage of the game, it is critical for YOU to understand how your BMS functions on at least a cursory level. Choose your BMS very carefully and periodically verify that it is operating properly. They're not all created equal. Make sure V sense lines are securely connected and free of corrosion. Just because your BMS says there was never a problem doesn't necessarily make it so. Avoid harnesses or ribbon cables between multiple modules if possible--they are problematic wherever they are used in any mobile electronics.
  5. Exposure to or generation of sufficient heat. I don't know exactly at what temperature gas formation begins in the electrolyte, but we spec a max storage temp of 80 (or 85?) degrees C and I suspect this is the reason. The hotter, the puffier--to a point. This is why soldering tabs poses a real hazard to cell health. If you feel you must solder, sink or blow the heat away from the body of the cell. Use a big iron that can make sufficient local heat quickly, before the whole mass of the cell gets hot. You might even get the cell warm enough to melt separator if not careful.
  6. No compression, not enough compression, improperly distributed compression. This is a pack/module design issue. Apply 10, maybe 15 psi to your cell stack end to end and then band snugly and evenly. Use hard endplates of some sort--never wrap cells directly or allow their shape to become distorted. Protect all areas of the pouch from impact damage. This obviously does not apply to cylindrical cells.

LiFePO4 prismatic cells

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LiFePO4 cylindrical cells

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LiFePO4 cell ageing

Derived (barely paraphrased) from wb9k's[5] post on endless sphere in the A123 thread[6]

Capacity loss is caused by the lithium that was available for storage becoming permanently plated on the cathode. Being unable to move within the cell it is no longer available to store energy. The impact of this plating is greater than the amount of lithium 'lost' to plating because not only is the lithium no longer available, it is also preventing access to that part of the cathode meaning Li that can still move has to take a longer path to reach the cathode. Lithium plating is one cause of increased cell resistance (there are others), a sign of worsening cell health.

There is no linear relationship between actual capacity loss and impedance rise. However some cell defects will also increase impedance.

Increasing cell resistance may cause a number of symptoms which may be confused with High Self Discharge.[7]

  1. Elevated Peukert Losses. As more energy per amount of current through the cell is lost as heat, the cells useable capacity decreases. So the apparent capacity loss is higher than the actual capacity loss of cycleable lithium. When used in low current applications (e.g. solar energy storage) the actual and apparent decrease in capacity will be small. In high current draw applications (like EV traction packs), the Peukert loss increases proportionally, so the apparent capacity loss increases much faster than the actual capacity loss.
  2. Greater voltage excursion under the same load. Due to increased cell resistancethe voltage will sag further under the same load than a cell in optimal condition. The inverse is also true, the voltage will be higher for the same amount of charging current applied. The cell will then rebound to a voltage further from the loaded and charging voltages. This, obviously, can look like high self discharge but is a different phenomenon.
  3. Absolute maximum current decrease.

Elevated impedance causes a more complex constellation of symptoms, some of which may be easy to confuse with High Self Discharge (HSD). Ohm's law (E=I/R) holds the key to understanding here.

1) Elevated Peukert losses. Because more energy per unit of current through the cell is lost as heat, less of the cell's capacity is actually USABLE. Thus, apparent capacity loss can be significantly greater than actual capacity loss caused by the loss of cycleable Li alone. In low current applications, the two numbers will be close together. In high current applications, Peukert losses increase in proportion, so apparent loss of capacity breaks further and further away from actual capacity loss as current increases.

2) Greater voltage excursion under the same load. Elevated resistance across the cell means that voltage will sag more under the same load than it did when the cell was healthier. Conversely, voltage will rise higher with the same amount of applied charge current than it did when it was healthier. At the same time, rebound/settling voltages will be further away from loaded/charging voltages. In other words, the cell will rebound to a voltage further away from loaded voltage, all else being equal. Similarly, voltage will settle farther from the charge voltage with the same charge applied. This can give the illusion of elevated self-discharge, but the phenomenon is actually not the same thing. Again, the greater the charge and load currents, the greater the effect becomes.

3) Absolute max current decreases. Because the cell's series resistance is elevated, the maximum possible current through the cell is decreased.

Just to confuse things further, there can be many factors that lead to impedance rise. Some are related to Li plating, others are not.

Lithium-ion

Lithium-ion (Li-ion) batteries have a greater energy density than Lithium Iron Phosphate batteries, but have more challenging needs to use safely. The ideal operating range of Li-ion batteries is between +15 and +45°C. The upper limit of temperature is particularly important as Li-ion batteries experience thermal runaway - an unstoppable chain reaction that can occur in milliseconds releasing the stored energy in the cell. This can produce temperatures of 400°C and a fire that is extremely difficult to put out. Thermal runaway can start as low as 60°C and becomes much more likely at 100°C

Risk factors for thermal runaway:

  • Short Circuits - either internally or externally
  • Overcharging
  • Excessive current draw or when charging

Li-ion pouch cells

Kokam produce high-performance Li-ion pouch cells[8]. These combine relative ease of use and pack construction with performance close to cylindrical cells.

Li-ion 18650 and other cylindrical cells

Cylindrical cells are favoured by Tesla, and are probably the main reason why their cars achieve such excellent performance. They are light, compact, powerful and expensive. Unfortunately, cylindrical cells are difficult (and potentially dangerous) to use in DIY conversions. There are two good reasons for this: thermal management and cell configuration.

As stated above, Li-ion cells are prone to thermal runaway. So you need perfect battery and thermal management to ensure that no cell ever exceeds the critical voltage or temperature. If this happens, a cell can short-circuit internally, releasing a lot of energy - potentially explosively. Furthermore, the individual cells are small, so need to be arranged in parallel. In the case of the Tesla Model S 85kW pack, there are 74 cells in parallel. Imagine if one of those cells fails and becomes short circuited internally. You now have 73 very high power cells all feeding in to that short circuit...

In fact, you don't have to imagine: you can watch this famous video instead (courtesy of Rich Rebuilds).

Cell voltages / Type





OEM modules

Using an OEM module means a lot of the difficulties and safety issues associated with battery design are taken care of e.g. cooling, clamping, etc.

Here is a handy list of OEM modules:

Manufacturer Model Capacity (kWh) Weight (kg) w (mm) d (mm) h (mm) Gravity (kg/kWh) Volume (L/kWh) Voltage (V) Current (cont A) Current (peak A) Cell arrangement Cell type Chemistry
Tesla Model S 85kWh 5.3 26 690 315 80 4.9 3.3 22.8 500 750 74p6s 18650 Li-ion
Tesla Model S 100kWh 6.4 28 680 315 80 4.4 2.7 22.8 870 86p6s 18650 Li-ion
Tesla Model 3 LR (inner) 19.2 98.9 1854 292 90 5.2 2.5 91.1 971 46p25s 2170 Li-ion
Tesla Model 3 LR (outer) 17.7 86.6 1715 292 90 4.9 2.5 83.9 971 46p23s 2170 Li-ion
Tesla Model 3 SR (inner) 13.0 58.9 1385 326 90 3.7 91.1 603 31p24s 2170 Li-ion
Tesla Model 3 SR (outer) 12.0 58.9 1380 344 90 3.8 83.9 603 31p24s 2170 Li-ion
Tesla Model 3 LFP (inner) 13.38 86 1860 323 81 6.4 83 161 23s Prismatic LiFePo4
Tesla Model 3 LFP (outer) 15.07 93.48 1948 323 81 6.2 93.5 161 25s Prismatic LiFePo4
Calb 4S3P 2.19 12 355 151 108 5.5 2.6 14.6 900 3p4s Pouch Li-ion
Calb 6S2P 2.19 12 355 151 108 5.5 2.6 22.2 600 2p6s Pouch Li-ion
Chevrolet Volt 2012 4 38 470 180 280 9.5 5.9 88.8 676 3p24s Pouch Li-ion
BMW i3 60Ah 2 13 410 310 150 6.5 9.5 28.8 210 350 2p8s Prismatic Li-ion
BMW i3 94Ah 4.15 28 410 310 150 6.7 4.6 45.6 409 12s Prismatic Li-ion
BMW i3 120Ah 5.3 28 410 310 150 5.3 3.6 45.6 360 12s Prismatic Li-ion
BMW PHEV 34Ah 2.0 13.05 368 178 102 6.525 3.34 59.0 16s Prismatic Li-ion
Jaguar iPace 2.5 12 340 155 112 4.8 2.4 10.8 720 1200 4p3s Pouch Li-ion
LG 4P3S 2.6 12.8 357 151 110 4.9 2.3 11 4p3s Pouch Li-ion
Mitsubishi Outlander 2.4 26 646 184 130 10.8 6.4 60 240 16s Li-ion
Nissan Leaf 24kWh 0.5 3.65 300 222 34 7.3 4.5 7.2 130 228 2p2s Pouch Li-ion LMO
Nissan Leaf 30kWh 1.25 300 222 34 3.6 14.4 2p4s Pouch Li-ion
Nissan Leaf 40kWh 1.6 8.7 300 222 68 5.4 2.8 14.4 314 2p4s Pouch Li-ion NMC
Nissan Leaf 62kWh 2.58 14.4 3p4s Li-ion
Porsche Taycan 2.77 12.7 390 155 115 4.9 2.3 21.9 360 600 2p6s Pouch Li-ion
PSA/Opel Peugeot E-208, Corsa E 2.73 12.7 390 150 115 4.6 2.5 21.9 2p6s / 1p6s Prismatic Li-ion
Volvo XC90 T8 2.01 12.1 300 180 150 6.0 4.0 59.2 170 340 16s Li-ion
VW Passet GTE 2.48 23.4 (with cooler plate)

10.8kg single

410 (C/P)

355 (S)

235 (C/P)

150 (S)

150 (C/P)

108 (S)

9.4 5.5 88.8 24s Prismatic Li-ion
VW Golf GTE 1.086 9.8 355 152 110 9.02 5.5 44 12s Prismatic Li-ion
VW Touareg 14,1 kWh 1.76 12.3 385 150 108 7.0 3.5 45.25 13s Prismatic Li-ion
VW id3/id4 55kWh, 62kWh 6.85 32 225 590 110 4.67 2.13 44.4 12s2p
VW id3/id4 82kWh 6.85 32 225 590 110 4.67 2.13 29.6 8s3p
Toyota Prius Prime 1.76 16.9 597 152 121 9.6 6.24 70.3
Renault Kangoo 3 16 310 210 140 5.3 3.03 29.6 8s Li-ion

References