For example, with a 24s pack, how fast could you spin a leaf or Tesla motor?
If that's a 'wrong question' I'm happy to be steered down the proper path

My current understanding is that using a lower voltage pack just means the inverter has to spend more energy boosting the voltage on the high bus to achieve the desired rpm/kv. However I don't feel confident in my understanding and feel like there must be limitations I'm not aware of, ie it's not that simple.